Crystal grids can be formed with any type of crystal - however, clear quartz single or double terminated points are preferred to direct the flow of energy.
Clusters or tumbled / polished stones can introduce a specific quality to the grid.
Choose stones that correspond to your intention for the grid. You could place a grid around a room to create a favourable energy for the function of the room. For example Rose Quartz to bring a loving energy to the bedroom, Amethyst for meditation, Citrine for studies, Hematite for grounding and protection.
See also Gemstones A-Z for some spiritual properties of crystals and gemstones